Everything about Potassium Titanyl Phosphate totally explained
Potassium titanyl phosphate (KTiOPO
4) or
KTP is a
nonlinear optical material which is commonly used for
frequency doubling diode pumped solid-state lasers such as
Nd:YAG and other
neodymium-doped
lasers. The material has a relatively high
optical damage threshold (~15 J/cm²), a great optical nonlinearity and excellent thermal stability. However, it's prone to
photochromic damage (called
grey tracking) during high-power 1064nm second-harmonic generation which tends to limit its use to low- and mid-power systems.
It is also frequently used as an
optical parametric oscillator for
near IR generation up to 4 µm. It is particularly suited to high power operation as an optical parametric oscillator due to its high damage threshold and large
crystal aperture. The high degree of
birefringent walkoff between the pump signal and idler beams present in this material limit its use as an optical parametric oscillator for very low power applications.
KTP is also used as an
electrooptic modulator, optical
waveguide material, and in
directional couplers.
KTP has
orthorhombic crystal structure. It is highly transparent for wavelengths between 350–2700 nm with a reduced transmission out to 4500 nm where the crystal is effectively opaque. Its
second harmonic generation (SHG) coefficient is about threfold higher than
KDP. It has a
Mohs hardness of about 5.
Crack-free fibers of KTP can be prepared from suitable
organometallic compounds (usually ethyl
alkoxides of potassium and titanium, and butyl
ester of
phosphoric acid).
KTP crystals coupled with or
Nd:YVO4 crystals are commonly found in green
laser pointers.
Other such materials include
KTiOAsO4.
Periodically poled potassium titanyl phosphate (PPKTP)
Periodically poled potassium titanyl phosphate (
PPKTP) is a new material for
nonlinear optics promising for various
photorefractive applications. It can be wavelength tailored for efficient second harmonic generation. The material is based upon
quasi-phase-matching, achieved by
periodic poling of the crystal, when a structure of regularly spaced
ferroelectric domains with alternating orientations is created in the material.
Other materials used for periodic poling are
wide band gap inorganic crystals like
lithium niobate (resulting in periodically poled lithium niobate, PPLN),
lithium tantalate, and some organic materials.
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